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العنوان
Heterocycles from acenaphenequinone and furantriones/
الناشر
Mahmoud Shoukry Moustafa,
المؤلف
Moustafa, Mahmoud Shoukry
هيئة الاعداد
مشرف / السيد حلمى العشرى
مشرف / نجوى راشد
مشرف / احمد مسعد
باحث / محمود شكرى مصطفى
الموضوع
Chemistry.
تاريخ النشر
1993
عدد الصفحات
.;ii+195+6p
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء
تاريخ الإجازة
1/1/1993
مكان الإجازة
جامعة الاسكندريه - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

from 218

from 218

Abstract

SUMMARY
1
This thesis includes three chapters, the first of which
deals with synthesis and reactions of acenaphthenequinone.
Chapter II is a discussion of the work that was carried out by the candidate. The goal of the work is divided into two parts dealing with the synthesis of heterocycles from acenaphthenequinone and furantriones respectively.
Regioisomeric formation of both acenaphtho[1,2—e][1,2,4J-- triazolo[3,4—c][1,2,4]triazines and acenaphtho[1, 2—eJ[1,2,4J-- triazolo[4,3—b][1,2,4]triazines have been achieved in the first part. A model study was carried out in order to confirm the regioselectivity. This study included the synthesis of both isomeric ring systems where the site of fusion in the biheterocycle is [3,4-c) and [4,3—b) as generally represented by 1 and 2 respectively.
/\ N
-
C3,4.cJ
(i )
The latter type of fusion [4,3—b] was achieved by the condensation of acenaphthenequinoné with 3,4—diainino--5-- methyl—4H-[1,2,4]triazole whereby the linear isomer 10—
.