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العنوان
Synthesis of Novel azo Dyes Containing the Pyridazine Ring
المؤلف
Dief, Sameh Mohammed Abd El-Hamid
هيئة الاعداد
باحث / سامح محمد عبد الحميد السيد ضيف
مشرف / أ.د /على عبدالحميد الديب
مشرف / أ.د/ صلاح الدين شقرة
مشرف / د/ طه ابو الفتوح أمين
الموضوع
Novel Azo Dyes Pyridazine Ring
تاريخ النشر
2014
عدد الصفحات
179P.:
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Inorganic Chemistry
تاريخ الإجازة
1/1/2014
مكان الإجازة
جامعة الزقازيق - كلية العلوم - الكيمياء
الفهرس
Only 14 pages are availabe for public view

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Abstract

Many different types of dyes were prepared based on pyrazolopyridazine moiety which may in turn used in many different appliocations not only as disperse dyes but also metal-complex dyes, reactive dyes, and azoic dyes.
The treatment of 3-diazo-4,5-diphenylpyrazolo[3,4-c]pyridazine with different active methylene compounds, ”cyclic, acyclic”, aromatic amines, cyclic amines, and phenols in ethanol with stirring yielded different colored azodyes. Azodyes of 3-diazo-4,5-diphenylpyrazolo [3,4-c]pyridazine also were prepared via first reacting the cyanoacetichydrazide with aromatic aldehyde such as benzaldehyde, o-chlorobenzaldehyde, p-nitrobenzaldehyde and p-N,N-dimethylbenzaldehyde in ethanol containing few drops of piperidine. Coupling of the condensation aceto-acetic hydrazide product with 3-diazo-4,5-diphenylpyrazolo[3,4-c]pyridazine.
On the other hand, Disazo dyes were prepared by the diazotization of 3-amino-4-((4,5-diphenyl-1H-pyrazolo[3,4-c]pyridazin-3-yl)diazen-yl)-1H-pyrazol-5(4H)-one, via nitrosyl sulfuric acid method followed by coupling with β-naphthol, ethyl cyanoacetate, and ethyl acetoacetate.
Metal dye complexes were also prepared from 1-((4,5-diphenyl-1H-pyrazolo[3,4-c]pyridazin-3-yl)diazenyl)naphthalen-2-ol with copper and cobalt salts.
Some of the prepared azo disperse dyes were applied to polyester fabric, and their spectral and color fastness properties measured which reflect in general the good dyeing behavior of such dyes .