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العنوان
Gamma Radiation Induced-Preparatio of Modified Acrylamide Polymeric Materials for The Treatment of WasteWater.
المؤلف
Emara, Amr Mohamed Said
هيئة الاعداد
باحث / عمرو محمد سعيد عمارة
مشرف / أ.د/ أحمد مؤمن المصرى
مشرف / أ.د/ثروت عيسى صيام
مشرف / د/ حسام الدين محمد عبد العزيز
الموضوع
TREATMENT OF WASTEWATER GAMMA RADIATION INDUCED-PREPARATION
تاريخ النشر
2014
عدد الصفحات
158p
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الفيزياء الذرية والجزيئية ، وعلم البصريات
تاريخ الإجازة
1/10/2014
مكان الإجازة
جامعة الزقازيق - كلية العلوم - الفيزياء
الفهرس
Only 14 pages are availabe for public view

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Abstract

The work carried out in the present thesis is based on preparation, characterization and applications of some modified resins such as: poly(acrylamide-acrylic acid) P(AAm-AA), poly(hydroxamic acid-acrylic acid) P(HA-AA) and poly(dithio-carbamate-acrylic acid) P(DTC-AA) resins.
Poly(acrylamide-acrylic acid) P(AAm-AA) as a polymeric resin was prepared by gamma radiation-initiated copolymer-rization of acrylamide-acrylic acid monomers in the presence of N,N’-methylene bisacrylamide (NMBA) as a crosslinker. It was studied at different experimental conditions such as: comonomer composition, comonomer concentration, crosslinker, and radiation doses. In this study, poly(hydroxamic acid-acrylic acid) P(HA-AA) and poly(dithiocarbamate-acrylic acid) P(DTC-AA) resins were prepared from the conversion of amide group in P(AAm-AA) by hydroxylamine hydrochloride and by the nucleophilic addition of carbon disulphide in an alkaline medium, respectively.
The functional groups on the prepared polymeric resins were confirmed by using Fourier transform infrared (FTIR) spectra. Thermogravimetric analyses (TGA), differential scanning calori-metry (DSC) measurements, and scanning electron microscopy (SEM) were performed to evaluate the properties of the prepared polymeric resins.