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العنوان
Preparation and characterization of modified mesoporous silica and its applications for the removal of some environmental pollutants /
المؤلف
EL-Sharifi, Fares Thabet Kaid.
هيئة الاعداد
باحث / فارس ثابت قايد الشريفى
مشرف / عوض إبراهيم أحمد
مشرف / أحمد محمد لطفى
مشرف / عوض إبراهيم أحمد
مشرف / أحمد محمد لطفى
الموضوع
Silica. Chemistry, Physical and theoretical.
تاريخ النشر
2014.
عدد الصفحات
206 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Physical and Theoretical Chemistry
تاريخ الإجازة
01/01/2014
مكان الإجازة
جامعة المنصورة - كلية العلوم - Department of Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

MCM-41 and BiVO4/MCM-41 (3, 8, 15, 25 and 35wt.%) samples were prepared by Mixed MCM-41 with different wt% of BiVO4 and then calcined at 550˚C for 6 hrs. And MCM-41/ BiVO4 (1, 5, 8, 10 and 15 wt%) samples were prepared by Mixed BiVO4 with different wt% of MCM-41 and then calcined at 550˚C. XRD shown Presence of sharp peak at 2θ =2.3 which implies the hexagonal pore structure of all samples. And two peaks at 2θ = 4.0o and 4.8o, respectively, due to highly ordered arrangement of hexagonal arrays and characteristic peaks for monoclinic scheelite phase are formed. The TEM and SEM images of MCM-41/BiVO4 and MCM-41/BiVO4 samples, show irregular and similar sphere particles, with nanosize nearly 2.4 nm, the degree of crystallinity of the samples increased with amount MCM-41content and BiVO4 content. EDX results, confirmed the purity of samples, FT-IR spectra of pure BiVO4 and MCM-41 /BiVO4 samples showed existence of MCM41 and BiVO4 . Experiments were conducted to investigate the activity of BiVO4/MCM-41 adsorbents for the removal of methylene blue (MB) and brilliant green from aqueous solutions. The photocatalytic activity of MCM-41/ BiVO4 photocatalysts was measured by the photodegradation of MB and BG under UV/visible light.