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العنوان
Synthesis Of Nitrogen Heterocycles from Carbonyl Compounds /
المؤلف
El Soccary, Nagwa Nabawy Ahmed.
هيئة الاعداد
باحث / نجوى نبوى احمد السكرى
مشرف / صلاح عبد الباقى
مشرف / محمد الصادق
مشرف / محمد عبد الرحمن
الموضوع
Nitrogen Carbonyl. Compounds.
تاريخ النشر
1990.
عدد الصفحات
234 p. :
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
الكيمياء
تاريخ الإجازة
1/1/1990
مكان الإجازة
جامعة الاسكندريه - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

from 234

from 234

Abstract

The first chapter reviews the reactions of amino sugars with B-dicarbonyl compounds as well as the chemis- try of Chapter II is a discussion of the work carried out by the candidate which consists of two parts. In the first part, candidate succeeded in the synthesis of a new heterocyclic hydrazine namely, 5-(D-arabino-tetrahydroxy- butyl)-2-methyl-3-pyrroy lhydrazine (I). It was allowed со react with different aromatic aldehydes to give the corresponding N-15-(D-arabino-tetrahydroxybutyl)-2-methyl- 3-pyrroyl Jarylaldehyde hydrazones (II). Destructive oxi- dation of the polyhydroxyalkyl chain of these hydrazones (II) was achieved by the use of sodium metaperiodate to afford the corresponding N-(5-formy1-2-methyl-3-pyrroyl)- arylaldehyde hydrazones (III). Their structures were con- firmed by condensation reaction with different acyl- hydrazines to afford the corresponding mixed bis (hydrazones) (IV 4-oxo-4,5,6,7- tetrahydroindoles.