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Abstract Supramolecular or self-assembled materials often result from a subtle balance of weak intermolecular interactions yielding to a large variety of ordered and disordered phases with many different physical, chemical or mechanical properties. Alkane urea inclusion compounds (UIC) are molecular composite structures where a ”host” framework of urea molecules accommodates ”guest” alkane molecules as long chains loosely held in a honey-comb like hexagonal network of adjacent channels. Most of the alkane-UICs are incommensurate or aperiodic, which means that the ratio of the host and guest periodicities is not a rational number M/N. As a consequence, very different types of short and long range ordering, as well as different phase transitions take place in these alkane-UICs just by changing the length of the alkane molecules. Even if these compounds are aperiodic by construction, periodicity can be recovered in superspaces of dimension greater than 3 and where full power of Fourier analysis can be used for crystallographic investigation. |