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العنوان
Photocatalytic Degradation of Methanol Solution Using Titanium Dioxide and Ultraviolet Rays \
المؤلف
Abdel Hady, Mohamed Abdel Basset Mohamed.
هيئة الاعداد
باحث / محمد عبد الباسط محمد عبد الهادي
mabdelbasset@yahoo.com
مشرف / محمد حسين عبد المجيد زكي
dr.mhzaki@gmail.com
مشرف / شعبان علي عطية نصير
مناقش / احمد امين عبد العظيم زعطوط
مناقش / نبيل محمود محمود عبد المنعم
الموضوع
Chemical Engineering.
تاريخ النشر
2019.
عدد الصفحات
86 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الهندسة (متفرقات)
تاريخ الإجازة
30/11/2019
مكان الإجازة
جامعة الاسكندريه - كلية الهندسة - الهندسة الكيميائية
الفهرس
Only 14 pages are availabe for public view

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Abstract

This thesis discusses the photocatalytic oxidation and degradation of Methanol using TiO2 particles / 254 nm UV lamp in a slurry type reactor in which the fine catalyst particles are suspended in the solution. Moreover, the effects of several process parameters such as Methanol initial concentration, TiO2 loading, initial pH of solution, and superficial liquid velocity on the photo-degradation reaction were studied to achieve maximum degradation efficiency. The solution COD was traced to measure the degradation process by being measured at various time intervals during the experiment duration. The results illustrated that the COD reduction percent increases with increasing the superficial liquid velocity however decreases with increasing the solution pH or the Methanol initial concentration. Furthermore, the COD reduction percent increases with increasing TiO2 loading up to 1.5 g/l then decreases with any further increase in the amount of TiO2. The maximum COD reduction percent was 77.5 % at 10 ppm, pH = 1, catalyst loading 1.5 g/l and superficial liquid velocity of 1.92 cm/s. The reaction order was determined utilizing Lagergren‘s rate equation and the linear pseudo second order reaction equation in which the reaction was found to be pseudo second order reaction.