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العنوان
ELECTROCHEMICAL AND THERMODYNAMIC STUDIES ON SOME ION PAIRS OF COBALT COMPLEXES IN DICARBOXYLATE MEDIA /
المؤلف
EL- HADIDY, AHMED AYOUB,
هيئة الاعداد
باحث / AHMED AYOUB EL- HADIDY
مشرف / M. F. AMIRA
مشرف / A.A. ZAGLOUL
مشرف / A. A. MAHMOUD
الموضوع
Density. THERMODYNAMIC. DICARBOXYLATE.
تاريخ النشر
2020.
عدد الصفحات
175 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء
تاريخ الإجازة
1/1/2020
مكان الإجازة
جامعة الاسكندريه - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

A general survey is given in Chapter I for classification of solvents,solute-solvent
interactions , properties of the used mixed solvent and importance of malic acid including the
effect of solvent on the dissociation reactions of malic acid and their thermodynamic
consequences , beside the thermodynamics of ionic associations have been reviewed .
Chapter II discusses the practical part of this work in which the electromotive force EMF
method used for the determination of both acid and ion-pair dissociation constants in
acetonitrile-water media of varying solvent composition (0-50 wt% of AN) and within the
temperature range ( 30-50 ℃). The EMF measurements have been performed with Crison pHmeter
MM 41 type read to ±0.1 mV, beside the method of preparations of the used solutions
and materials have been discussed.