الفهرس 
AcknowledgmentOnly 14 pages are availabe for public view
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Abstract
The pincer ligand 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine (bpmt) was used to synthesize the novel [Na(bpmt)2][AuCl4] complex through the self-assembly method. The novel [Na(bpmt)2][AuCl4] complex was obtained as highly crystalline product in which Its structure was analyzed using single crystal X-ray diffraction, FTIR, and NMR spectroscopic techniques, in addition to elemental analysis and Hirshfeld topology analysis. In this complex, the Na(I) ion is hexa-coordinated with two tridentate N-pincer ligands (bpmt). The two bpmt ligand units are meridionally coordinated to Na(I) via one short Na-N(s-triazine) and two slightly longer Na-N(pyrazole) bonds, resulting in a distorted octahedral geometry around the Na(I) ion. In the coordinated bpmt ligand, the s-triazine core is not found to be coplanar with the two pyrazole moieties. Additionally, the two bpmt units are strongly twisted from one another by 64.94(8)°.